Nematic and Smectic Mesophase from Calamitic Bisazobenzene Liquid Crystal: Synthesis and Characterization of 1- Methoxyhexyloxy-4'-(4-Phenylazo) Azobenzene Hybrid Molecule
Abstract
A new hybrid calamitic liquid crystal material with rod-shape bisazobenzene moieties as a core has been synthesized and characterized by spectroscopic methods. The mesomorphic properties were investigated by differential scanning colorimetry, polarizing optical microscopy and X-Ray diffraction. The rod-shaped molecule 1- methoxyhexyloxy-4`-(4-phenylazo)azobenzene was prepared by diazotization of 4-phenylazoaniline, coupling with phenol and subsequent etherification of 1-Bromohexyloxy-4`-(4-phenylazo)azobenzene in methanol. The presence of enantiotropic nematic and smectic A mesophases were confirmed by the textures and X-Ray diffraction.
DOI: https://doi.org/10.3844/ajassp.2009.561.564
Copyright: © 2009 Sidik Silong, Abdulsalam Abubakar Salisu, Muhamad Zaki Ab Rahman, Lutfor Rahman and Mansor Ahmad. This is an open access article distributed under the terms of the
Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
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Keywords
- liquid crystal
- bisazobenzene
- calamitic
- nematic phase
- smectic phase